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ring opening to radical LXXX. High-MW polymers are obtained only when R1 and/or R2 are substituents such as COOR or CN, which stabilize radicals [Cho, 2000; Endo and Suga, 1989; Endo et al., 1989; Sanda and Endo, 2001]. Vincylcyclopropanes undergo polymerization exclusively through the double bond with cationic and Ziegler Natta (Chap. 8) initiators. Anionic polymerization of cyclopropanes with electron-withdrawing substituents proceeds exclusively through ring opening [Penelle and Xie, 2000]. The polymerization of a variety of other monomers, such as vinyloxiranes, vinyllactones, dihydrofurans, and bicyclobutanes, have been studied [Cho, 2000]. Kricheldorf and coworkers have found that some heterocyclic compounds containing two reactive bonds behave as bifunctional reactants in a ROP that proceeds by a step polymerization mechanism [Kricheldorf, 2000]. An example is the polymerization of 2,2-dibutyl-2stanna-1,3-dioxepane with an aliphatic diacid chloride:

7-105

We have no early census quotations for Italy, but by the time the Venetian prestiti were quoted in the late thirteenth century their range was not very different from minimum commercial and deposit rates Minimum commercial rates rose sharply in the late sixteenth century Chart 3C shows that French minimum commercial rates, also dominated by Italian bankers, remained high in fact, above Netherlands and Italian rates in the thirteenth and fourteenth centuries, were low in the early sixteenth century, and then rose sharply with the late sixteenthcentury defaults The rates on French rentes declined over the centuries English rates are included on this chart for convenience only; they were very little influenced by French or other continental rates before the seventeenth century The earliest reported English long-term rates in the early sixteenth century were far higher than most continental minima, but in the seventeenth century they declined sharply.

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Once again, all the same considerations apply as with the original Speak & Spell covered previously, in Project 1.

The surprising aspect of this polymerization is that the polymer product is cyclic with number-average molecular weight above 10,000.

7-11

As noted in Sec. 2-15, there has been considerable interest in the synthesis of inorganic and partially inorganic polymers. Some of the polymers have been synthesized by ROP.

These charts do not reflect the great rise and fall of whole civilizations such as were embraced within Chart 1, which summarized ancient interest rates The time span was shorter The political entities, instead of great empires, were at first local; most of the time they were not even organized as great nations These charts cover a period which contained the gradual evolution of modern banking techniques, but it breaks off just as these were becoming fully formed and effective The terminal date of 1700 is artificial The history of interest rates in Western Europe is continued in succeeding chapters..

The commercial importance of polysiloxanes (silicone polymers) was discussed in Sec. 2-12f. The higher-MW polysiloxanes are synthesized by anionic or cationic polymerizations of cyclic siloxanes [Bostick, 1969; Kendrick et al., 1989; Noll, 1968; Saam, 1989; Wright, 1984]. The most commonly encountered polymerizations are those of the cyclic trimers and tetramers, for example, for octamethylcyclotetrasiloxane

As before, mount all components prior to soldering. All controls should be easy to mount if located as shown in the main layout illustration (refer to Figure 16-1).

7-106

THE ORIGIN OF THE FUNDED DEBT AND OF THE BANK OF ENGLAND England was transformed financially as well as politically by the Revolution of 1688. Under the reigns of the Tudors and the Stuarts, no money or investment markets comparable to those of Antwerp, Lyons, and Amsterdam had appeared in London. On the Continent during the fifteenth and sixteenth centuries the Italians had played a leading role in developing a complicated system of private international banking. During the seventeenth century the Dutch had developed effective state finance based on confidence in a popular government s ability to pledge the resources of a town, province, or nation. It was now England s turn to achieve financial leadership. Within the first few decades of the eighteenth century, England improved upon the Italian banking techniques and upon the Dutch principles of funded debt. The city of London learned how to mobilize the savings of the people for commercial and for national objectives. Because this transformation has an important bearing on the history of interest rates, it is presented here in some detail and with retrospective background. Furthermore, the history of English credit and interest rates in the eighteenth and nineteenth centuries is discussed in greater detail than that of other European countries because of the leading role that England then played in the development of all modern money markets. Up to the last decade of the seventeenth century England had no money market, no substantial bank, and no organized national debt. Stuart kings borrowed haphazardly from goldsmiths on short term; sometimes they paid

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